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61.
Application of an efficient strategy based on liquid–liquid extraction,high‐speed counter‐current chromatography,and preparative HPLC for the rapid enrichment,separation, and purification of four anthraquinones from Rheum tanguticum 下载免费PDF全文
Tao Chen Yongling Liu Denglang Zou Chen Chen Jinmao You Guoying Zhou Yulin Li 《Journal of separation science》2014,37(1-2):165-170
This study presents an efficient strategy based on liquid–liquid extraction, high‐speed counter‐current chromatography, and preparative HPLC for the rapid enrichment, separation, and purification of four anthraquinones from Rheum tanguticum. A new solvent system composed of petroleum ether/ethyl acetate/water (4:2:1, v/v/v) was developed for the liquid–liquid extraction of the crude extract from R. tanguticum. As a result, emodin, aloe‐emodin, physcion, and chrysophanol were greatly enriched in the organic layer. In addition, an efficient method was successfully established to separate and purify the above anthraquinones by high‐speed counter‐current chromatography and preparative HPLC. This study supplies a new alternative method for the rapid enrichment, separation, and purification of emodin, aloe‐emodin, physcione, and chrysophanol. 相似文献
62.
基于光滑粒子流体动力学方法,构建齿轮泵壳体及内部流体的粒子模型,对内啮合齿轮泵在不同工况下的流量特性进行数值模拟。首先设置了均匀分布的油泵出入口压强,计算得到的流量结果与试验结果吻合,且在中低转速下流量与转速呈线性关系;针对高转速下油泵流量降低的问题,通过适当减小周期模型内部的流体粒子数反映流量降低,获得了与试验值相吻合的连续转速流量的模拟结果;针对影响齿轮泵性能的间隙和空化现象,结合模型特点给出了相应的近似处理方法。通过以上研究,将SPH方法成功地应用于滑油泵问题的分析计算。 相似文献
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For a reaction-diffusion system that serves as a 2-species Lotka-Volterra diffusive competition model, suppose that the corresponding reaction system has one stable boundary equilibrium and one unstable boundary equilibrium. Then it is well known that there exists a positive number c?, called the minimum wave speed, such that, for each c larger than or equal to c?, the reaction-diffusion system has a positive traveling wave solution of wave speed c connecting these two equilibria if and only if c?c?. It has been shown that the minimum wave speed for this system is identical to another important quantity - the asymptotical speed of population spread towards the stable equilibrium. Hence to find the minimum wave speed c? not only is of the interest in mathematics but is of the importance in application. It has been conjectured that the minimum wave speed can be determined by studying the eigenvalues of the unstable equilibrium, called the linear determinacy. In this paper we will show that the conjecture on the linear determinacy is not true in general. 相似文献
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We study the diffusive logistic equation with a free boundary in higher space dimensions and heterogeneous environment. Such a model may be used to describe the spreading of a new or invasive species, with the free boundary representing the expanding front. For simplicity, we assume that the environment and the solution are radially symmetric. In the special case of one space dimension and homogeneous environment, this free boundary problem was investigated in Du and Lin (2010) [10]. We prove that the spreading-vanishing dichotomy established in Du and Lin (2010) [10] still holds in the more general and ecologically realistic setting considered here. Moreover, when spreading occurs, we obtain best possible upper and lower bounds for the spreading speed of the expanding front. When the environment is asymptotically homogeneous at infinity, these two bounds coincide. Our results indicate that the asymptotic spreading speed determined by this model does not depend on the spatial dimension. 相似文献
66.
众所周知Lamb波在复合材料中的传播呈各向异性的特点,经典有限元法模拟这类问题效率不高,所以,本文采用谱有限元法进行研究。先建立了一种新的谱有限板单元,该单元以Gauss-Lobatto-Legendre点作为节点,使质量矩阵是对角矩阵;另外,该单元采用了扩展的位移场,能够较好地模拟板结构的三维特性。然后,对复合材料板结构中Lamb波在对称模式与反对称模式下的传播速度进行了求解,将计算结果与Mindlin板谱单元的结果以及三维弹性理论的结果进行了比较,并讨论了Lamb波在反对称层合板中的传播特点。最后,模拟了Lamb波在含和不含损伤复合材料层合板中的传播,数值结果表明所建立的谱有限板单元可以较好地模拟出Lamb波在复合材料板结构中的传播特性。 相似文献
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Jinqian Yu Jinqiang Zhang Xiaowei Sun Chenghong Xiao Xiao Wang Tao Zhou 《Journal of separation science》2020,43(7):1265-1274
The roots of Dipsacus asper Wall as a commonly used traditional Chinese medicine are used for tonifying liver and kidney and strengthening bones and muscles. However, an effective separation strategy for comprehensive and rapid separation of the main active compounds from the roots of D. asper is nonexistent. This investigation provided an effective separation method based on AB‐8 macroporous resin column chromatography using different ratios of ethanol in water and two different modes of high‐speed countercurrent chromatography with salt‐containing solvent system for rapid enrichment and separation from the roots of D. asper. The macroporous resin column chromatography was performed on AB‐8 resin using ethanol in water ratios of 10, 30, 40, 50, and 80% as the optimized enrichment conditions for iridoid glycosides and triterpenoid saponins with different polarities. For high‐speed countercurrent chromatography separation, the conventional and recycling modes were combined together to develop a strategy for 12 compounds ( 1 – 12 ) from the enriched parts of 30, 40, and 80% ethanol, including six high‐polarity iridoid glycosides ( 1 – 6 ) using inorganic salt‐containing solvent system and six triterpenoid saponins ( 7 – 12 ). Recycling high‐speed countercurrent chromatography separation was successfully applied to separate two isomers ( 9 and 10 ) after 11 cycles. 相似文献
70.
提出了一种利用脉冲光声技术测量固体介质中声速的方法,建立了由YAG激光器和超声探测器组成的实验系统,脉冲激光在固体表面产生脉冲超声波,通过测量脉冲声波在固体内多次反射后的出射信号及固体的厚度,即可算出固体介质中的声速.对黄铜及铝的测量结果表明,这是一种准确性较高的固体介质中声速测量方法.该测量方法可作为综合设计性物理实... 相似文献